Switching of macroscopic molecular recognition selectivity using a mixed solvent system
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چکیده
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چکیده ندارد.
15 صفحه اولSolvent effects on the molecular recognition of anions.
Anion recognition of two flexible diols in different solvents and binary mixtures were examined. Binding constants (K) in CD3CN and CDCl3 are surprisingly similar, and CD3CN-solvent mixtures led to reduced values of K that are smaller than in either pure solvent. A surprising U-shaped dependence is observed.
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ژورنال
عنوان ژورنال: Nature Communications
سال: 2012
ISSN: 2041-1723
DOI: 10.1038/ncomms1841